Safety Data Sheet

Issue Date:   01-Jan-2010	Revision Date:   02-Oct-2013	Version   1

1. IDENTIFICATION

Product Identifier 	
Product Name	pH7 FLOOR AND CARPET NEUTRALIZER

Other means of identification 	
SDS #	SJJ-006

UN/ID No	UN1805

Recommended use of the chemical and restrictions on use 	 Recommended Use	Floor and carpet neutralizer.

Details of the supplier of the safety data sheet 	 Supplier Address
Smith & Jones Janitorial
1 Biloxi Sq.
W. Columbia, SC 29170

Emergency Telephone Number 	
Company Phone Number	1-803-822-8500
Emergency Telephone (24 hr)	INFOTRAC 1-352-323-3500 (International)
1-800-535-5053 (North America)

2. HAZARDS IDENTIFICATION

Appearance   Light green liquid	Physical State   Liquid	Odor   Odorless

Classification 	

Acute toxicity - Inhalation (Dusts/Mists)	Category 4	
Skin corrosion/irritation	Category 1   Sub-category C	
Serious eye damage/eye irritation	Category 1	

Signal Word
Danger

Hazard Statements
Harmful if inhaled
Causes severe skin burns and eye damage

Precautionary Statements - Prevention
Use only outdoors or in a well-ventilated area
Do not breathe dust/fume/gas/mist/vapors/spray
Wash face, hands and any exposed skin thoroughly after handling
Wear protective gloves/protective clothing/eye protection/face protection

Precautionary Statements - Response
Immediately call a poison center or doctor/physician
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
Immediately call a poison center or doctor/physician
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
Wash contaminated clothing before reuse
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
Immediately call a poison center or doctor/physician
IF SWALLOWED: rinse mouth. Do NOT induce vomiting

Precautionary Statements - Storage
Store locked up

Precautionary Statements - Disposal
Dispose of contents/container to an approved waste disposal plant

WHMIS Classification
Class D - Division 2 Class E

Other Hazards
Harmful to aquatic life with long lasting effects
Harmful to aquatic life

Unknown Acute Toxicity
7% of the mixture consists of ingredient(s) of unknown toxicity

3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical Name	CAS No	Weight-%	
Water	7732-18-5	63	
Phosphoric acid	7664-38-2	20	
Citric Acid	77-92-9	10	
Malic Acid	6915-15-7	7	

**If Chemical Name/CAS No is "proprietary" and/or Weight-% is listed as a range, the specific chemical identity and/or percentage of composition has been withheld as a trade secret.**

4. FIRST-AID MEASURES

First Aid Measures

Eye Contact	Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Immediately call a poison center or doctor/physician.

Skin Contact	IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Wash skin with soap and water. If skin irritation persists, call a physician. Wash contaminated clothing before reuse.

Inhalation	IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Immediately call a poison center or doctor/physician.

Ingestion	IF SWALLOWED: rinse mouth. Do NOT induce vomiting. Seek medical attention.

Most important symptoms and effects

Symptoms	Causes severe skin burns and eye damage. Harmful if inhaled.

Indication of any immediate medical attention and special treatment needed

Notes to Physician	Treat symptomatically.

5. FIRE-FIGHTING MEASURES

Suitable Extinguishing Media
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Unsuitable Extinguishing Media Not determined.

Specific Hazards Arising from the Chemical
Product is not flammable.

Hazardous Combustion Products   Contact with metals may evolve flammable hydrogen gas.

Sensitivity to Mechanical Impact No.
Sensitivity to Static Discharge	No.

Protective equipment and precautions for firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures 	

Personal Precautions	Use personal protective equipment as required.

Environmental Precautions	See Section 12 for additional Ecological Information. See Section 13: DISPOSAL CONSIDERATIONS.

Methods and material for containment and cleaning up 	

Methods for Containment	Prevent further leakage or spillage if safe to do so.

Methods for Clean-Up	Dike and contain spill. Collect and place in suitable, properly labeled container for recovery or disposal.

7. HANDLING AND STORAGE

Precautions for safe handling

Advice on Safe Handling	Handle in accordance with good industrial hygiene and safety practice. Use personal protection recommended in Section 8. Use only outdoors or in a well-ventilated area. Do
not breathe vapors or spray mist. Wash face, hands, and any exposed skin thoroughly after handling. Wash contaminated clothing before reuse.

Conditions for safe storage, including any incompatibilities

Storage Conditions	Store locked up.

Incompatible Materials	Contact with metals may evolve flammable hydrogen gas. Strong oxidizing agents.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Exposure Guidelines 	

Chemical Name	ACGIH TLV	OSHA PEL	NIOSH IDLH	
Phosphoric acid
7664-38-2	STEL: 3 mg/m3
TWA: 1 mg/m3	TWA: 1 mg/m3
(vacated) TWA: 1 mg/m3
(vacated) STEL: 3 mg/m3	IDLH: 1000 mg/m3
TWA: 1 mg/m3
STEL: 3 mg/m3	
Citric Acid
77-92-9	-	15 mg / m3 (Total)	-	

Appropriate engineering controls

Engineering Controls	Apply technical measures to comply with the occupational exposure limits. Eyewash stations. Showers.

Individual protection measures, such as personal protective equipment

Eye/Face Protection	Wear safety glasses with side shields (or goggles).

Skin and Body Protection	Wear rubber or neoprene gloves. Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact.

Respiratory Protection	Ensure adequate ventilation, especially in confined areas. In case of inadequate ventilation wear respiratory protection.

General Hygiene Considerations Wash contaminated clothing before reuse. Wash face, hands and any exposed skin thoroughly after handling.

9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties

Physical State	Liquid		
Appearance	Light green liquid	Odor	Odorless	
Color	Light green	Odor Threshold	Not Applicable	

Property 	
pH
Melting Point/Freezing Point
Boiling Point/Boiling Range
Flash Point
Evaporation Rate Flammability (Solid, Gas) Upper Flammability Limits	Values 	
3.0 +/- 0.8
<   0   °C   /   <32   °F
>   100   °C   /   >212   °F None
Not available
Liquid-not applicable
Not applicable	Remar	
Lower Flammability Limit	Not applicable		
Vapor Pressure Vapor Density Specific Gravity Water Solubility
Solubility in other solvents
Partition Coefficient
Auto-ignition Temperature Decomposition Temperature Kinematic Viscosity
Dynamic Viscosity
Explosive Properties
Oxidizing Properties	8.2 mmHg
<1
1.3
Not determined
Not determined Not applicable Not available Not determined Not determined Not determined
Not an explosive
Not determined	
(Air=1)	

ks   • Method 	

10. STABILITY AND REACTIVITY

Reactivity 	
Not reactive under normal conditions.

Chemical Stability
Stable under recommended storage conditions.

Possibility of Hazardous Reactions
Contact w/ common metals may generate flammable hydrogen gas.

Hazardous Polymerization	Hazardous polymerization does not occur.

Conditions to Avoid
Keep out of reach of children.

Incompatible Materials
Contact with metals may evolve flammable hydrogen gas. Strong oxidizing agents.

Hazardous Decomposition Products
None known based on information supplied.

11. TOXICOLOGICAL INFORMATION

Information on likely routes of exposure 	

Product Information

Eye Contact	Causes severe eye damage. Skin Contact	Causes severe skin burns. Inhalation	Harmful if inhaled.
Ingestion	Do not taste or swallow.

Component Information 	

Chemical Name	Oral LD50	Dermal LD50	Inhalation LC50	
Water
7732-18-5	> 90 mL/kg   ( Rat )	-	-	
Phosphoric acid
7664-38-2	= 1530 mg/kg   ( Rat )	= 2730 mg/kg   ( Rabbit )	> 850 mg/m3    ( Rat ) 1 h	
Citric Acid
77-92-9	= 3000 mg/kg   ( Rat )	-	-	

Information on physical, chemical and toxicological effects 	

Symptoms	Please see section 4 of this SDS for symptoms.

Delayed and immediate effects as well as chronic effects from short and long-term exposure 	

Carcinogenicity	This product does not contain any carcinogens or potential carcinogens as listed by OSHA, IARC or NTP.

Numerical measures of toxicity
Not determined

Unknown Acute Toxicity	7% of the mixture consists of ingredient(s) of unknown toxicity.

12. ECOLOGICAL INFORMATION

Ecotoxicity 	
Harmful to aquatic life with long lasting effects.

Component Information 	

Chemical Name	Algae/aquatic plants	Fish	Toxicity to
microorganisms	Crustacea	
Phosphoric acid
7664-38-2		3 - 3.5: 96 h Gambusia
affinis mg/L LC50		4.6: 12 h Daphnia magna
mg/L EC50	
Citric Acid
77-92-9		1516: 96 h Lepomis
macrochirus mg/L LC50 static		120: 72 h Daphnia magna
mg/L EC50	

Persistence/Degradability
Not determined.

Bioaccumulation
Not determined.

Mobility

Chemical Name	Partition Coefficient	
Citric Acid
77-92-9	-1.72	

Other Adverse Effects
Not determined

13. DISPOSAL CONSIDERATIONS

Waste Treatment Methods

Disposal of Wastes	Disposal should be in accordance with applicable regional, national and local laws and regulations.

Contaminated Packaging	Disposal should be in accordance with applicable regional, national and local laws and regulations.

California Hazardous Waste Status 	

Chemical Name	California Hazardous Waste Status	
Phosphoric acid
7664-38-2	Corrosive	

14. TRANSPORT INFORMATION

Note  	Please see current shipping paper for most up to date shipping information, including exemptions and special circumstances. Note: Protect product from freezing during transportation.

DOT 	
UN/ID No	UN1805
Proper Shipping Name	Phosphoric acid solution
Hazard Class	8
Packing Group	III

IATA 	
UN/ID No	UN1805
Proper Shipping Name	Phosphoric acid solution
Hazard Class	8
Packing Group	III

IMDG 	
UN/ID No	UN1805
Proper Shipping Name	Phosphoric acid solution
Hazard Class	8
Packing Group	III
Marine Pollutant	This material may meet the definition of a marine pollutant

15. REGULATORY INFORMATION

International Inventories 	
Not determined

US Federal Regulations 	

CERCLA
This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302)

Chemical Name	Hazardous Substances RQs	CERCLA/SARA RQ	Reportable Quantity (RQ)	
Phosphoric acid
7664-38-2	5000 lb		RQ 5000 lb final RQ
RQ 2270 kg final RQ	

SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA).   This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372

CWA (Clean Water Act)
This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42)

Component	CWA - Reportable
Quantities	CWA - Toxic Pollutants	CWA - Priority Pollutants	CWA - Hazardous
Substances	
Phosphoric acid
7664-38-2 ( 20 )	5000 lb			X	

US State Regulations 	

California Proposition 65
This product does not contain any Proposition 65 chemicals.

U.S. State Right-to-Know Regulations

Chemical Name	New Jersey	Massachusetts	Pennsylvania	
Phosphoric acid
7664-38-2	X	X	X	

16. OTHER INFORMATION

NFPA   	Health Hazards
Not determined
HMIS  	Health Hazards
Not determined

Flammability Not determined Flammability Not determined

Instability
Not determined Physical Hazards Not determined

Special Hazards Not determined Personal Protection Not determined

Issue Date:	01-Jan-2010
Revision Date:	02-Oct-2013
Revision Note:	New format

Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.

End of Safety Data Sheet